Synthesis, Spectral, Thermal, and a Crystalline Structure of Complexes Containing [Mec(CH2PPh2)3Cu(I)]
- Publication Type
- Original research
- Authors
- Ismail Warad
- Omar H Abd-Elkader
- Ahmed Boshaala
- Nabil Al-Zaqri
- Belkheir Hammouti
- Taibi Ben Hadda
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The preparation of new [MeC(CH2PPh2)3CuCl] 1 and its derivatives was carried out directly by mixing of CuCl and MeC(CH2PPh2)3 ligand in dry THF, the neutral precursor 1 served to prepare [MeC(CH2PPh2)3Cu(NCCH3)]BF4 2 and [MeC(CH2PPh2)3Cu(PCH2Ph)3]BF4 3. These complexes are characterized on the basis of elemental analysis, IR, EDS, 1H, 13C and 31P{1H}NMR, FAB-MS, TG/DTA and single-crystal X-ray diffraction studies. Complex 1 crystallizes in the Orthorhombic unit cells with the space group Pna2(1). The structural behavior of MeC(CH2PPh2)3 ligand in the formed complexes during the coordination reaction was monitored by 31P{1H}NMR in CDCl3 at room temperature for the first time.
Journal
- Title
- Research on Chemical Intermediates February 2013, Volume 39, Issue 2, pp 721-732
- Publisher
- --
- Publisher Country
- Palestine
- Publication Type
- Both (Printed and Online)
- Volume
- --
- Year
- 2013
- Pages
- --