Synthesis, Spectral And Structural Charcterization Of Novel Dichloro-Ruthenium(II)/Triphenylphosphine/(3,4-Diaminophenyl)(Phenyl)Methanone Complex
Publication Type
Original research
Authors
  • Ismail Warad
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The novel trans-[Cl2Ru(II)(PPh3)2(3,4-diaminophenyl)(phenyl)methanone] complex was obtained by reacting RuCl2(PPh3)3 with equimolar amounts of (3,4-diaminophenyl)(phenyl)methanone as diamine co-ligand in CH2Cl2. One of the PPh3 ligand was quantitatively exchanged by (3,4-diaminophenyl)(phenyl)methanone, even when excess diamine was added. The trans-RuCl2 desired complex was characterized on the basis of elemental analysis, elemental analysis, FAB-MS, IR, UV-vis, 1H, 13C and 31P{1H}NMR.
Journal
Title
J. Mater. Environ. Sci. 4(5) (2013) 822-827
Publisher
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Publisher Country
Palestine
Publication Type
Both (Printed and Online)
Volume
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Year
2013
Pages
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