Synthesis, Characterization, Crystal Structure And Chemical Behavior of [1,1-Bis(Diphenylphosphinomethyl)Ethene]Ruthenium(II) Complex Toward Primary Alkylamine Addition
- Publication Type
- Original research
- Authors
- Ismail Khalil Warad
- M. Rafiq H. Siddiqui
- Saud Al-Resayes
- Abdulrahman Al-Warthan
- Refaat Mahfouz
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Reaction of the ruthenium phosphine complex [RuCl2(PPh3)3] 1 with an unsaturated functionalized diphosphine ligand, namely 1,1-bis(diphenyl-phosphinomethyl)ethene, H2C=C(CH2PPh2)2, (dppme) gave trans-Cl2Ru(dppme)2 2. Complex 2 served as a precursor for the synthesis of trans-Cl2Ru(dppme)(alkylamine)2 complexes 3–5 by reaction with RNH2. All these complexes were characterized by spectroscopic techniques and by elemental analysis. The solid-state structure of complex 2 was determined by X-ray crystallography.
Journal
- Title
- Transition Metal Chemistry, Volume 34, Issue 3 , pp 347-352
- Publisher
- --
- Publisher Country
- Palestine
- Publication Type
- Both (Printed and Online)
- Volume
- --
- Year
- 2009
- Pages
- --